• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Part of a timepiece and timepiece, a piece of jewelery or jewelery comprising an alloy comprising by weight at least 750 ‰ of gold, characterized in that the alloy comprises at least 200 ‰ of copper, between 4 ‰ and 35 ‰ of palladium and between 1 ‰ and 16 ‰ of indium.
    公开号:CH707537B1
    申请号:CH00158/14
    申请日:2014-02-06
    公开日:2017-01-13
    发明作者:Ricard Jean-François；Dubos Pascal
    申请人:Rolex Sa；
    IPC主号:
    专利说明:

    The invention relates to all or part of a timepiece, a piece of jewelery or jewelry including a rose gold alloy, as a watch.
    State of the art
    [0002] The color of gold alloys depends on their content of alloying elements. For AuCuAg 18ct alloys for example, a copper content greater than 180 ‰ and a silver content of about 40 ‰ gives them a red color. The color changes to pink then to yellow if the copper content decreases from 180 ‰ to 150 ‰ then from 150 ‰ to 60 ‰ and if the silver content increases from 40 ‰ to 150 ‰. We found that watch cases or wristbands made from these common gold alloys tended to undergo a gradual change in their color under the action of tap water, seawater, pool water, salt water or soapy water.
    One of the aims of the invention is to improve the resistance to a color change of a timepiece, jewelery or jewelry made in a pink gold alloy and subject, in progress. use, to weakly aggressive aqueous media.
    Another object of the invention is to define a pink gold alloy whose pink has an aesthetic appearance as attractive as possible.
    Brief description of the invention
    For this purpose, the invention is based on a timepiece, jewelery or jewelery comprising an alloy comprising by weight at least 750 ‰ of gold characterized in that the alloy comprises at least 200 ‰ of copper , between 4 ‰ and 35 ‰ of palladium and between 1 ‰ and 16 ‰ of indium.
    The invention is precisely defined by the claims.
    Brief description of the figures
    These objects, features and advantages of the present invention will be set forth in detail in the following description of particular embodiments made in a non-limiting manner in relation to the attached figures among which:<tb> Fig. 1 <SEP> shows three experimental decolorization curves respectively obtained on an alloy 13Pd (curve 1), 5In (curve 2) and 20Pd10In (curve 3).<tb> Fig. 2 <SEP> represents a table of discoloration test results obtained after 20 days on different alloys.<tb> Figs. 3 and 4 <SEP> represent discoloration test results obtained after 40 days on different alloys.<tb> Fig. <SEP> represents the discoloration obtained after 40 days as a function of the sum of the palladium and indium components of different alloys.<tb> Fig. 6 <SEP> illustrates the discoloration obtained after 40 days for different alloys according to their palladium and indium levels.<tb> Fig. 7 <SEP> schematically positions several alloys on a graph to illustrate the color obtained for these different alloys.
    Embodiments of the invention will now be presented, from specific examples and results of empirical experiments. For this, ingots are prepared by vacuum static casting (melting in a graphite crucible and cooling under nitrogen). Samples are cut from the ingot in the raw state of casting. The surface is prepared by polishing. A typical sample has a square section of 20 mm x 20 mm x 5 mm. All tests are carried out on casting alloys without subsequent deformation or heat treatment, and without the addition of usual grain refiners.
    The crystallographic analysis of the samples is carried out with an X-ray diffractometer with Cu anode. Metallographic control and stoichiometry analysis of the phases are performed by MEB-EDX scanning electron microscopy.
    The color variations are measured with a spectrocolorimeter with integrating sphere. The color is conventionally defined by a point in the CIELAB space consisting of a green-red axis on the abscissa, a yellow-blue axis on the y-axis and an axis representative of the contrast (see CIE15 report: 2004 established by the International Commission on Illumination). The measurements were all performed using the following convention: illuminant D65 and standard observer 10 ° (CIE1964). The color differences ΔE are defined by the DE2000 (equation 8.36, paragraph 8.3, CIE15: 2004 report). A measurement of the color difference is made between fresh (cast and polished) samples and accelerated salt spray aging samples, with NIHS 96-50 exposure at 45 ° C with a saline solution containing 50 g / l of pure NaCl. The 750Au250Cu alloy serves as a reference base.
    The following convention is used for the designations of the alloys:For 18ct (750Au) alloys, indicate the content of the additive elements in weight percent before the element symbol. The copper content is not indicated because it corresponds to the balance. However, this copper content will advantageously be greater than or equal to 200 ‰. Example: 10In is a 750Au240Cu10In alloy;For non-18ct alloys, indication of the Au content in weight per cent before the element, then indication of the additive elements according to the preceding point;The value ranges that will be mentioned later may include or exclude their terminals, which will not always be specified.
    The table in fig. 2 and the graph of FIG. 1 summarize the results obtained after aging with salt spray for various massive ingots in gold alloy. The tables in fig. 3 and 4 show other results obtained on alloys after aging for 40 days in salt spray.
    The 13Pd alloy is very interesting, from the point of view of the color obtained and the discoloration. This discoloration as a function of time is represented by the curve 1 of FIG. 1.More generally, an alloy composed of at least 750 ‰ of gold, of copper, and with a Palladium content (Pd) defined by: Pd ≤ 20 ‰ or Pd ≤ 15 ‰, or 5 ‰ ≤ Pd ≤ 15 ‰, or 8 ‰ ≤ Pd ≤ 15 ‰ or 11 ‰ ≤ Pd ≤ 15 ‰ is advantageous.
    AuCuIn alloys are interesting because the results highlight that In allows to form a single-phase alloy with Au and Cu. In particular, the alloy 5In derives little, as it appears on the curve 2 of FIG. 1, and already shows an improvement over the reference of a 250Cu alloy. Indeed, the tests carried out show that there is an optimum at the level of the color drift between 5 and 20 ‰ of In, in particular around 10 ‰, with a preferred interval between 7 ‰ ≤ In 15 ‰. More generally, an alloy composed of at least 750 ‰ of gold, of copper, and with an indium content (In) defined by: In ≤ 20 ‰ or In ≤ 15 ‰, or 5 ‰ ≤ In <20 ‰ or 7 ‰ ≤ In ≤ 15 ‰ is advantageous.
    Quaternary or quinternary alloys comprising palladium are also very interesting. In particular, as is apparent from the results of FIGS. 2 to 4 relating to the time resistance to discoloration, the alloys 20Pd10In, 10Pd 5In 5Ca, 15Pd 10In 5Ca, 5Pd 10In 5Ca, 10Pd 5In, 20Pd 10In 0.1Si, 20Pd 10In 1Ca, 20Pd 10In 0.5Ca, 20Pd 10In 0.02Si show weak drifts and are interesting. AuCuPdIn alloys, such as 20Pd 10In alloy or 10Pd 5In alloy, are particularly interesting.
    More generally, an alloy composed of at least 750 ‰ of gold, copper, palladium and indium is interesting, particularly when the sum of the Pd and In levels is less than or equal to 45 ‰. , or even 40 ‰, or even 35 ‰ or even 30 ‰, and / or when the sum of the Pd and In levels is between 15 ‰ and 40 ‰, or even 20 ‰ and 35 ‰, and / or or when the alloy comprises at least 1 ‰ of Pd and 1 ‰ of In, or even at least 5 ‰ of Pd and 5 ‰ of In.
    More generally, an alloy composed of at least 750 ‰ of gold, copper, palladium and at least one element Y, Y being chosen from Ca, Zr, or In is interesting, particularly when the sum Palladium content and Y element (s) is less than or equal to 40 ‰, or even 35 ‰, or even 30 ‰ or even 25 ‰), or even 20 ‰, even 17 ‰, or even 15 ‰ or even 13 ‰, and / or when the sum of the levels of Pd and element (s) Y is in the range between 15 ‰ and 40 ‰, or even 20 ‰ and 35 ‰, and / or when the alloy comprises at least 1 ‰ of Pd and 1 ‰ of the element Y or even at least 5 ‰ of Pd and 5 ‰ of the element Y.
    More generally, an alloy composed of at least 750 ‰ of gold, copper, palladium and at least one element Y, Y being chosen from In, Ca, Sr, Si, Ti, Zr, or Mg is interesting, especially when the sum of the Palladium levels and the element (s) Y is less than or equal to 40 ‰, even 35 ‰, or even 30 ‰, even 25 ‰, even 20 ‰, or even 17 ‰ or 15 ‰, or even 13 ‰, and / or when the sum of the levels of Pd and element (s) Y is in the interval between 15 ‰ and 40 ‰, or even 20 ‰ and 35 ‰, and / or when the alloy comprises at least 1 ‰ Pd and 1 ‰ or Y elements or even at least 5 ‰ of Pd and 5 ‰ or Y elements.
    The quaternary or quinternary alloys with In are also interesting. More generally, an alloy composed of at least 750 ‰ of gold, copper, indium and at least one element Y, Y being chosen from Ca, Sr, Si, Ti, Zr, Mg or Pd is interesting. , especially when the sum of the rates of Indium and element Y is less than or equal to 40 ‰, even 35 ‰, even 30 ‰, even 25 ‰, even 20 ‰, even 17 ‰, even 15 ‰, or even 13 ‰, and / or when the sum of the rates of In and the element (s) Y is between 15 ‰ and 40 ‰, or even 20 ‰ and 35 ‰, and / or when the alloy comprises at least 1 ‰ of In and 1 ‰ of element (s) Y, or even at least 5 ‰ of In and 5 ‰ of element (s) Y.
    The following ternary alloys titrating 18ct or more are particularly interesting:AuCuPd with Pd <20 ‰, more particularly with 5 ‰ ≤ Pd <20 ‰, more particularly with 5 ‰ ≤ Pd ≤ 15 ‰AuCuIn with In <20 ‰, more particularly with 5 ‰ ≤ In <20 ‰, more particularly with 7 ‰ ≤ In ≤ 15 ‰
    AuCuPdIn quaternary alloys containing 18ct or more are particularly interesting:in particular with the sum of the Pd and In levels of less than or equal to 45 ‰, even 40 ‰, even 35 ‰ or even 30 ‰;and / or with the sum of the Pd and In levels in the range between 15 ‰ and 40 ‰, or even 20 ‰ and 35 ‰;and / or with at least 1 ‰ of Pd and 1 ‰ of In, or even at least 5 ‰ of Pd and 5 ‰ of In;in particular the 20Pd10In alloy or the 10Pd5In alloy.
    The quaternary or quinternal alloys titrating 18 and or more following are also particularly interesting:AuCuXY, where X is Pd or In, and Y is at least one of Pd (if X ≠ Pd), In (if X ≠ In), Ca, Sr, Si, Ti, Zr, or Mg,in particular with the sum of the rates X + Y ≤ 40 ‰and / or with the concentrations for Pd, In and Y element (s): Pd, In ≤ 40 ‰ and Y (Y ≠ In, Pd) ≤ 10 ‰;and / or with at least 1 ‰ of Pd and 1 ‰ of the element or elements Y, or even at least 5 ‰ of Pd and 5 ‰ of the element or elements Y.
    Quinternary AuCuPdInX alloys where X is selected from Ca, Sr, Si, Ti, Zr, Mg are also interesting.
    Finally, it should be noted that other alloys comprising more than four elements may be equally interesting, for example five or six, obtained by replacing the Y element of the quaternary compounds mentioned above by n elements Y1, Y2,... , Yn, the elements Yi being preferably selected from Ca, Sr, Si, Ti, Zr, Mg, Pd or In, and so that the sum of the rates of all the elements excluding Au and Cu is less than or equal to 40 ‰. Such alloys include especially alloys comprising the components Au, Cu, Pd, In, and X, where X is at least one member selected from Ca, Sr, Si, Ti, Zr, Mg.
    Finally, it is noted that the alloys combining both Palladium and Indium are particularly advantageous compared to alloys comprising only one or the other of these components, as illustrated by curve 3 of FIG. fig. 1 and the results of the different tables of figs. 2 to 4.
    In particular, it appears that an alloy comprising by weight at least 750 ‰ of gold, also comprising copper, palladium and indium, the sum of the palladium and indium levels being less than or equal to 45 ‰, or even less than or equal to 35 ‰, or even less than or equal to 30 ‰, and / or the sum of the palladium and indium levels being between 20 ‰ and 35 ‰, is advantageous. Such an alloy may comprise an indium content defined by: 7 ‰ ≤ rate of In ≤ 15 ‰. On the other hand, such an alloy may comprise gold, copper, palladium and calcium and / or silicon, so that the sum of the rates of all elements out of gold and copper is less than or equal to 40 ‰.
    Figs. 5 and 6 illustrate in a complementary manner the interest of combining palladium and indium and make it possible to visualize the optimal quantities.
    Fig. 5 illustrates the discoloration obtained after 40 days for different alloys, according to the sum of the levels of palladium and indium they comprise. It appears that the best results are obtained for a sum greater than or equal to 15 ‰, are further improved for a sum greater than or equal to 20 ‰. The 20 ‰ -35 ‰ intervals combine several high-performance alloys, and the reduced 25 ‰ -33 ‰ range brings together even better results.
    Fig. 6 gives additional indications on the sharing of these levels between the two components palladium and indium. It appears that the best results are obtained for a palladium content of between 15 ‰ and 30 ‰, even between 19 ‰ and 29 ‰, and an indium content of between 1 ‰ and 15 ‰ inclusive. Note that when using a small amount of indium, for example between 1 ‰ and 10 ‰, or between 1 ‰ and 6 ‰, and even between 1 ‰ and 4 ‰, there is a advantageous significant effect due to its combination with palladium.
    In addition to the very important previous considerations relating to the maintenance of the color of an alloy over time, it is also necessary to take into account the quality of the color itself obtained for an alloy considered, and particularly the aesthetic of the rose color obtained. Indeed, the addition of the various components mentioned above has an effect not only on the maintenance in time of the color, but also on the color itself of the alloy. For example, the addition of palladium in a pink gold alloy has the effect of desaturating the pink color, even to make the color of the alloy to gray, and the addition of indium has the effect of drifting towards the yellow of a pink alloy.
    FIG. 7 schematically illustrates these remarks. The coordinate a * is on the abscissa and the coordinate b * on the ordinate. Note that this color can be measured against reference colors, and can also be subject to a visual examination, the aesthetic effect obtained being particularly noticeable by visual observation. The first reference alloy is a conventional 18-carat yellow gold alloy, positioned on the left and top of the diagram, near the y-axis, corresponding to a strong yellow cast. The second reference alloy is a very red 18-carat gold alloy, comprising 250 ‰ copper, positioned on the right and bottom of the diagram, near the abscissa axis. It is noted that the addition of a relatively large amount of palladium, as illustrated by the example of the 40 Pd alloy, has the effect of greatly attenuating the saturation of the color, to finally give a very pale alloy, of grayish appearance. After several tests, it appears useful to use an amount of palladium less than or equal to 29 ‰ to maintain a satisfactory pink color, which is manifested by a positioning in the area 5 highlighted in FIG. 7. Thus, a 20Pd alloy is positioned for example at a satisfactory pink color. It is noted that the addition of a small amount of indium to this alloy 20Pd has little effect on the color, as schematically illustrates the positioning of the 20Pd10In alloy in FIG. 7, which is very close to the alloy 20Pd. As a note, if we had added 10Pd to the alloy 20Pd, to obtain a 30Pd alloy, replacing the 10In added, the desaturation of the pink color would have been very pronounced. This also makes it possible to conclude that from the point of view of color, it is advantageous to combine indium and palladium, rather than to consider a single equivalent quantity of palladium, it appears moreover that, to maintain a satisfactory pink color , the sum of the rates of the two components should not be too important, otherwise the rose will be degraded compared to the desired pink. It is thus preferable to remain less than or equal to 35 ‰, or even 33 ‰, 30 ‰, 29 ‰ or 25 ‰, these values representing different levels, all satisfactory, but allowing successively to improve the result. In addition, it is also interesting to choose a sufficient minimum amount of the sum of the levels of the palladium and indium components, to avoid that the pink color tends to red. For this, it appears that a minimum of 15 ‰ is highly recommended, and that it is preferable to choose a value greater than or equal to 20 ‰ or even 25 ‰. In summary of these considerations, the sum of the palladium and indium levels is advantageously included in the intervals between 15 ‰ -35 ‰, even between 20 ‰ and 35 ‰, or even between 25 ‰ and 33 ‰, which represent choices. interesting for obtaining a satisfactory pink color of a gold alloy, these terminals can be included or excluded.
    Finally, the alloys of pink gold combining palladium and indium are interesting because they allow both to achieve a satisfactory aesthetic color and fade little over time. The precise quantities for each of these two components and their sum represent compromises between the reduction of the discoloration and the aesthetics of the desired pink color. We note, however, that the intervals for this sum of palladium and indium levels which allow both to reach a satisfactory pink color and a slight discoloration are between 15 ‰ and 35 ‰, or even between 20 ‰ and 35 ‰, even between 25 ‰ and 33 ‰, as shown in previous analyzes. In these ranges, a high palladium content, greater than or equal to 15 ‰, or even greater than or equal to 19 ‰, is favorable to the reduction of discoloration. On the contrary, a low palladium content, less than or equal to 20 ‰, or even less than or equal to 19 ‰ or 18 ‰, is favorable to the aesthetics of the pink color. In compromise, a palladium level of between 19 ‰ and 25 ‰ inclusive forms a good solution.
    The above considerations can be adapted to any amount of copper greater than or equal to 180 ‰, especially for a relatively small amount of copper, for example between 180 ‰ and 200 ‰. However, we note that it is possible to relax some of the previous ranges in the event that a significant amount of copper is imposed, especially greater than or equal to 200 ‰. Indeed, in this case, a pink color can be more easily obtained, even using larger amounts of palladium and indium components tending to degrade, as explained above. As a result, if the amount of copper Cu is greater than or equal to 200 ‰, it is possible to obtain suitable alloys with a palladium content of between 4 ‰ and 35 ‰ and an indium content of between 1 ‰ and 16 ‰.
    Thus, the invention relates to a timepiece, jewelery or jewelery comprising an alloy comprising by weight at least 750 ‰ of gold, characterized in that the alloy also comprises at least 200 ‰ of copper , between 4 ‰ and 35 ‰ of palladium and between 1 ‰ and 16 ‰ of indium.
    In all cases, if it is desired to ensure the anti-fading effect (anti-aging over time) optimal, it then becomes advantageous to choose a relatively high palladium content, which can then be between 19 ‰ and 35 ‰ or between 21 ‰ and 35 ‰. If we also want to avoid too much degradation of the aesthetics of the pink color, we can lower the upper threshold of the palladium level, closer to 30 ‰ if possible and preferably strictly under 30 ‰. The optimal ranges taking into account these constraints are then a palladium content between 23 ‰ and 31 ‰ inclusive, or even between 23 ‰ and 29 ‰ inclusive, or even between 23 ‰ and 27 ‰ inclusive, to converge around a value of 25 ‰ which appears a good compromise. Note that when using a small amount of indium, for example between 1 ‰ and 10 ‰, or between 1 ‰ and 6 ‰, and even between 1 ‰ and 4 ‰, there is a advantageous significant effect due to its combination with palladium according to the above rates.
    The above considerations were made from example of 18-carat pink gold, 750 ‰ or gold. As a variant, the results remain relevant for a higher amount of gold, especially between 750 ‰ and 800 ‰, or even 750 ‰ and 770 ‰.
    The above compositions mention only the majority elements of the alloy, to which can be added at least one grain refining element according to the knowledge of the skilled person, which gives other embodiments of the invention. the invention. This grain refining element may be present, for example, at most at the rate of 2 ‰, or even 1 ‰, of at least one element chosen by way of example from Ru, Ir, Re, Co, V and Mo. elements such as Ir, Re or Ru make it possible to guarantee the fineness of the grain and to avoid porosities, without appreciably modifying the hardness, nor to affect the color, which is advantageous with respect to the desired object.
    On the other hand, as explained above, the alloys could further comprise other components, in addition to the aforementioned components Au, Cu, Pd and In, and any grain refiners, among Ca, Sr, Si, Ti, Zr, Mg. Advantageously, the sum of the rates of all the elements of the alloy excluding gold and copper is less than or equal to 40 ‰. Alternatively, the alloy may consist of these only four components Au, Cu, Pd, In, with one (or more) possible (s) refiner (s) grain.
    The various figures also illustrate a particular technical effect obtained with the addition of calcium Ca and / or silicon Si, in a very small amount, on the reduction of the discoloration of the alloys cited by way of example. A very small quantity, especially less than or equal to 10 ‰, or even 7 ‰, or even 5 ‰, for calcium, and / or less than or equal to 2 ‰, or even 0.5 ‰ for silicon, is sufficient to significantly reduce discoloration with the time of the alloys illustrated, without having any noticeable effect on the color itself, since a sufficient copper content, preferably greater than or equal to 180 ‰, more preferably greater than or equal to 200 ‰, is used . As a note, this effect of the Ca and Si components is also true of any other pink gold alloy, not necessarily comprising palladium and / or indium.
    As an additional remark, it is noted that such a pink gold alloy according to the embodiments of the invention advantageously does not include silver, which would induce the negative effect of yellowing the color of the alloy and even to make this color tend towards an unsightly greenish color, moving it away from the desired pink. In addition, as appears at the bottom of the table of FIG. 3 from a test carried out with an example of alloy 40Ag, it appears that the silver has no very effective effect on the behavior over time of the color, compared to other alloys studied. So there are two good reasons to exclude money from all of the achievements proposed above. However, alloys containing small amounts of money are not totally excluded since they could still take back the advantages mentioned above, if they are preponderant over the effect of money. The same conclusion is obtained for manganese. Other tests have also shown that zinc, chromium, or iron have no effect on the behavior over time of the color.
    Finally, in all the preceding embodiments, the alloys described will therefore be particularly effective for making all or part of a timepiece, such as a watch case, a bracelet, a watch, etc., or a piece of jewelery or jewelery. Naturally, this realization of a timepiece, jewelery or jewelry, means the manufacture of all or a significant part of the thickness of a timepiece, not a simple surface coating. The tests studied and described previously relate to massive volumes of certain alloys. Thus, the parts considered comprise a large amount of alloy, are advantageously in the form of a massive alloy capable of being deformed and to be polished, including in particular at least a portion of thickness greater than or equal to 0.1 mm .
    权利要求:
    Claims (13)
    [1]
    1. Part of a timepiece, a piece of jewelery or jewelery comprising an alloy comprising by weight at least 750 ‰ of gold, characterized in that the alloy comprises at least 200 ‰ of copper, between 4 ‰ and 35 ‰ ‰ of palladium and between 1 ‰ and 16 ‰ of indium.
    [2]
    2. Part of a timepiece, piece of jewelery or jewelery according to the preceding claim, characterized in that the alloy comprises between 19 ‰ and 35 ‰, or even between 21 ‰ and 35 ‰, or even between 23 ‰ and 31 ‰, or between 23 ‰ and 27 ‰, of palladium and between 1 ‰ and 16 ‰ of indium, even between 1 ‰ and 10 ‰ of indium, even between 1 ‰ and 6 ‰ of indium, or even 1 ‰ and 4 ‰ of indium.
    [3]
    3. Part of a timepiece, piece of jewelery or jewelery according to one of the preceding claims, characterized in that the alloy does not include silver and / or in that the alloy does not understand of manganese.
    [4]
    4. Part of a timepiece, piece of jewelery according to one of the preceding claims, characterized in that the piece has at least one solid part composed of said alloy and comprising a thickness greater than or equal to 0, 1 mm.
    [5]
    5. Part of a timepiece, piece of jewelery or jewelery according to one of the preceding claims, characterized in that the sum of the palladium and indium levels of the alloy is between 15 ‰ and 35 ‰, even between 20 ‰ and 35 ‰, even 25 ‰ and 33 ‰.
    [6]
    6. Part of a timepiece, piece of jewelery according to one of the preceding claims, characterized in that the alloy further comprises at least one grain refining element, in particular selected from Ru, Ir, Re, Co, V and Mo.
    [7]
    7. Part of a timepiece, jeweler's piece according to the preceding claim, characterized in that the rate of grain refining elements is less than or equal to 2 ‰, or even less than or equal to 1 ‰.
    [8]
    8. Part of a timepiece, piece of jewelery or jewelery according to one of the preceding claims, characterized in that the alloy consists of- gold, copper, palladium, indium, orGold, copper, palladium, indium and at least one grain refining element, orGold, copper, palladium, indium, and at least one Y element chosen from calcium Ca, strontium Sr, silicon Si, titanium Ti, zirconium Zr or magnesium Mg, or inGold, copper, palladium, indium, and at least one Y element chosen from calcium Ca, strontium Sr, silicon Si, titanium Ti, zirconium Zr or magnesium Mg, and at least one grain refining element.
    [9]
    9. Part of a timepiece, piece of jewelery or jewelery according to one of claims 1 to 7, characterized in that the alloy comprises gold, copper, palladium, indium and at least one Y element, Y being selected from Ca, Sr, Si, Ti, Zr, and Mg.
    [10]
    10. Part of a timepiece, piece of jewelery according to claim 8 or 9, characterized in that the alloy comprises calcium, with a calcium level less than or equal to 10 ‰, or even 7 ‰ , or 5 ‰ and / or silicon, with a silicon content less than or equal to 2 ‰, or even less than or equal to 0.5 ‰.
    [11]
    11. Part of a timepiece, piece of jewelery according to one of the preceding claims, characterized in that the sum of the rates of all the elements of the alloy excluding gold and copper is less than or equal to 40 ‰.
    [12]
    12. Part of a timepiece, piece of jewelery or jewelery according to one of claims 1 to 4, characterized in that the sum of the palladium and indium levels of the alloy is less than or equal to 45 ‰, even less than or equal to 35 ‰, even less than or equal to 30 ‰, or even less than or equal to 25 ‰.
    [13]
    13. Timepiece, characterized in that it comprises a part according to one of the preceding claims, and in that it is a watch.
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    JP6716071B1|2019-08-16|2020-07-01|ラブロ コロマー ジャウム|Ornaments|
    法律状态:
    2014-08-29| PK| Correction|Free format text: RECTIFICATION INVENTEUR |
    2014-10-15| PK| Correction|Free format text: ERFINDER BERICHTIGT. |
    2018-12-14| PFA| Name/firm changed|Owner name: ROLEX SA, CH Free format text: FORMER OWNER: ROLEX SA, CH |
    优先权:
    申请号 | 申请日 | 专利标题
    EP13154296|2013-02-06|
    EP13155142|2013-02-13|
    EP14150827|2014-01-10|
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